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BUMHS MDCAT 2023
BUMHS MDCAT 2023 Chemistry Portion
Each section/part of the Booklines MCQs for a chapter covers different topics, so please make sure to attempt all sections/parts.
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1. Which ionic radii is the smallest one? (BUMHS 2023 Che)
Al+++ has the smallest ionic radius because it has a higher positive charge, causing a greater pull on its electrons, reducing the radius.
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2. Thermodynamically the most stable form of carbon is: (BUMHS 2023 Che)
Graphite is the most thermodynamically stable form of carbon at room temperature and normal pressure.
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3. The overall charge on transition state in SN2 reaction is? (BUMHS 2023 Che)
The transition state in an SN2 reaction involves a negatively charged species because the nucleophile attacks the electrophile, forming a pentavalent transition state with a negative charge.
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4. Why do electrons have opposite spins when they are in the same orbital? (BUMHS 2023 Che)
Electrons in the same orbital must have opposite spins according to the Pauli Exclusion Principle. This minimizes repulsion and stabilizes the electron configuration by creating opposite magnetic fields.
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5. The solubility of carboxylic acid in water gradually decreases with: (BUMHS 2023 Che)
As the molecular mass of a carboxylic acid increases, its solubility in water decreases because larger molecules tend to be less soluble in polar solvents like water.
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6. What is the common name of 1,2,3-propanetriol? (BUMHS 2023 Che)
1,2,3-Propanetriol is commonly known as glycerol, a trihydric alcohol used in various industries like cosmetics and pharmaceuticals.
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7. Which of the following is not an endothermic reaction? (BUMHS 2023 Che)
The combustion of methane is an exothermic reaction, releasing energy in the form of heat, unlike the other endothermic processes listed.
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8. Which order of reaction obeys the expression t1/2 = 1/Ka? (BUMHS 2023 Che)
The half-life of a second-order reaction is inversely proportional to the concentration of the reactant (Ka), following the given mathematical relationship.
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9. Which of the following acid can show cis-trans isomerism? (BUMHS 2023 Che)
Maleic acid, which is a type of unsaturated dicarboxylic acid, exhibits cis-trans isomerism due to the restricted rotation around the carbon-carbon double bond.
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10. The system in which three angles and axes are unequal is called? (BUMHS 2023 Che)
The triclinic system is characterized by three axes that are unequal in length and none of the angles between them are 90°. This makes the system highly unsymmetrical compared to the cubic and other crystal systems.
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11. What is the quantum number for the unpaired electron of chlorine atom (n, l, m)? (BUMHS 2023 Che)
The quantum numbers for the unpaired electron in chlorine, which is in the 3p orbital, are n = 3, l = 1, and m = +1.
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12. The polar part of the soap and detergents dissolve in water molecules due to: (BUMHS 2023 Che)
The polar head of soap molecules forms hydrogen bonds with water molecules, allowing it to dissolve in water.
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13. The general electronic configuration of halide ions is: (BUMHS 2023 Che)
Halide ions have a complete octet, meaning their electronic configuration ends in ns2 np6.
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14. Which of the following statement is true about Grignard reagent (RMgX)? (BUMHS 2023 Che)
Grignard reagents are highly reactive with water and are therefore prepared in anhydrous ether to prevent their decomposition.
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15. Which of the following is carbon atom of a Carbonyl group? (BUMHS 2023 Che)
In a carbonyl group (C=O), the carbon atom is sp2 hybridized due to its bonding configuration, where it forms one sigma bond with oxygen and two sigma bonds with other atoms.
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16. For every reaction occurring in the human body there is at least one type of: (BUMHS 2023 Che)
Enzymes, which are biological catalysts, facilitate nearly every chemical reaction in the human body, playing a crucial role in metabolic processes.
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17. When aqueous solution of NaCl is electrolysed, what happens at the cathode? (BUMHS 2023 Che)
During the electrolysis of an aqueous NaCl solution, hydrogen gas is produced at the cathode due to the reduction of water.
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18. The hydrocarbon which has isolated rings and is aromatic? (BUMHS 2023 Che)
Triphenylmethane consists of isolated benzene rings, and the presence of these rings contributes to its aromaticity.
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19. Which functional group is characteristic of ester? (BUMHS 2023 Che)
Esters are characterized by the functional group -COOR, where a carbonyl group is bonded to an alkoxy group (-OR).
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20. Which product is formed when RMgX reacts with CO2? (BUMHS 2023 Che)
The reaction of a Grignard reagent (RMgX) with carbon dioxide (CO2) produces a carboxylic acid after hydrolysis.
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21. A set of postulates that explain the behavior of ideal gas is called: (BUMHS 2023 Che)
The Kinetic Molecular Theory explains gas behavior based on the motion and interaction of particles, which is central to understanding ideal gases.
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22. Why first ionization energy of Beryllium is higher than Boron? (BUMHS 2023 Che)
Beryllium has a fully filled 2s orbital, which provides extra stability, making its first ionization energy higher than Boron, which has a partially filled p-orbital.
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23. Number of primary carbon atoms present in isobutane is? (BUMHS 2023 Che)
In isobutane (C4H10), there are three primary carbon atoms, which are those bonded to only one other carbon atom.
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24. Which one of the following has no cleavage plane? (BUMHS 2023 Che)
Copper, being a metal, has a structure that does not exhibit cleavage planes, unlike crystalline ionic solids such as NaCl.
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25. Which of the following metals does not react with water? (BUMHS 2023 Che)
Beryllium (Be) does not react with water, unlike metals such as sodium (Na) and calcium (Ca), which readily react with water to produce hydrogen gas and a hydroxide.
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26. The acylium ion has a positive charge and acts as? (BUMHS 2023 Che)
The acylium ion (RCO+) is an electrophile due to its deficiency of electrons, making it seek out electron-rich species.
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27. Methanol is prepared from carbon monoxide and hydrogen. The catalyst used for this reaction is? (BUMHS 2023 Che)
The catalytic process of converting carbon monoxide and hydrogen into methanol is typically done using zinc oxide (ZnO) in combination with chromium oxide (Cr2O3).
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28. What is the fact due to which the branching decreases boiling point? (BUMHS 2023 Che)
Branching reduces the boiling point because it decreases the surface area of molecules, leading to weaker van der Waals forces between them.
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29. Acetic acid is weak acid than sulphuric acid because of which of the following reasons? (BUMHS 2023 Che)
Acetic acid is a weaker acid compared to sulfuric acid because it ionizes to a lesser degree, releasing fewer hydrogen ions in aqueous solutions.
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30. Which of the following occurs when carbonyl compounds react with HCN? (BUMHS 2023 Che)
When carbonyl compounds such as aldehydes or ketones react with hydrogen cyanide (HCN), a chiral cyanohydrin product is formed.
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31. At room temperature, Glycerin boils at 290°C. What is the boiling point of glycerin under vacuum distillation at 50 torr? (BUMHS 2023 Che)
The boiling point of a substance decreases under reduced pressure, so under vacuum at 50 torr, glycerin boils at a significantly lower temperature than its normal boiling point.
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32. Which statement about a 4d orbital is correct? (BUMHS 2023 Che)
A 4d orbital can accommodate up to 10 electrons, following the general rule that d orbitals hold 10 electrons.
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33. Protein content of human milk is about: (BUMHS 2023 Che)
Human milk contains approximately 2.4% protein, which supports the growth and development of infants.
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34. Which of the following is a bidentate ligand? (BUMHS 2023 Che)
Hydrazine (NH2-NH2) acts as a bidentate ligand as it can form two bonds with a metal center.
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35. sp2 hybrid carbon atom is present in: (BUMHS 2023 Che)
In propanol, the carbon atom forming the double bond is sp2 hybridized, a common feature in molecules with double bonds (C=C).
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36. Which one is incorrect for actual yield being less than theoretical yield due to: (BUMHS 2023 Che)
A pure substance should ideally provide the maximum theoretical yield under perfect conditions, thus purity does not cause a reduced yield. Losses in yield are typically due to side reactions, mechanical losses, or incomplete reactions.
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37. Hess’s law states the same thing as: (BUMHS 2023 Che)
Hess’s Law is a restatement of the First Law of Thermodynamics, which states that energy cannot be created or destroyed, only transferred or transformed.
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38. Group IB is called the coinage metals. Which one is not true about this group? (BUMHS 2023 Che)
Coinage metals like copper, silver, and gold are not strong reducing agents. Instead, they are more commonly used for their high resistance to oxidation.
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39. Which of the following is not true about Canal rays? (BUMHS 2023 Che)
Canal rays (positive ions) do cause mechanical motion, as their movement and interaction can produce mechanical effects.
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40. Which of the following characteristic of carbonyl oxygen increases by base-catalyzed reaction? (BUMHS 2023 Che)
In a base-catalyzed reaction, the carbonyl oxygen becomes more nucleophilic due to the increased electron density around it.
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41. Temperature increase in an exothermic reversible reaction, shifts the equilibrium to: (BUMHS 2023 Che)
In an exothermic reaction, increasing the temperature favors the reverse reaction (towards reactants) as the system tries to absorb the excess heat.
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42. The equilibrium stage that is not affected by temperature is called? (BUMHS 2023 Che)
In dynamic equilibrium, the rates of the forward and reverse reactions are equal, and changes in temperature can shift the equilibrium but do not affect its dynamic nature.
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43. Why do transition elements form alloys so easily? (BUMHS 2023 Che)
The similar atomic sizes of transition elements allow them to replace one another in the crystal lattice, enabling easy alloy formation.
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44. In which method the rate of reaction involving ions can be studied? (BUMHS 2023 Che)
The rate of reactions involving ions can be studied using electrical conductivity, as the presence of ions changes the conductivity of the solution.
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45. Which of the following acids has the smallest dissociation constant? (BUMHS 2023 Che)
Acids with halogens such as bromine are generally weaker compared to those with more electronegative halogens, resulting in a smaller dissociation constant for BrCH2CH2COOH.
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46. What is the reactivity state of Phenols? (BUMHS 2023 Che)
Phenols are less reactive than alcohols because the aromatic ring delocalizes the lone pair of electrons on the oxygen atom, reducing its reactivity.
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47. Which of the following carbon atom is sp2 hybridized? (BUMHS 2023 Che)
In graphite, each carbon atom is sp2 hybridized, forming planar structures with delocalized pi electrons contributing to its conductivity.
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48. The solubility of KClO3 is decreased by adding: (BUMHS 2023 Che)
Adding a common ion (K+) through KCl decreases the solubility of KClO3 by the common ion effect.
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49. How many moles of a gas occupy 30.57 L at 55°C and 0.83 atm? (BUMHS 2023 Che)
Using the ideal gas law PV = nRT, and plugging in the values for pressure, volume, temperature, and the gas constant, the number of moles is calculated as 0.94 mol.
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50. Air at sea level is dense. This is practical application of: (BUMHS 2023 Che)
Boyle’s law explains that at constant temperature, the pressure of a gas is inversely proportional to its volume, which relates to the density of air at sea level.
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51. What do we mean by the term ‘delocalised electrons’ in benzene? (BUMHS 2023 Che)
In benzene, the delocalized electrons exist in the pi bonding system, where they are free to move above and below the plane of the ring.
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52. What is the weight of oxygen that is required for the complete combustion of 3.2 kg of methane? (BUMHS 2023 Che)
In the combustion of methane, oxygen is consumed at a ratio of approximately 16 grams of oxygen for every 4 grams of methane, resulting in 12.8 kg of oxygen for 3.2 kg of methane.
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53. Which of the following pair is iso-structural? (BUMHS 2023 Che)
Both SO3 and BF3 have a trigonal planar structure, making them iso-structural.
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